Like Tom said, using just only urea isn´t mostly any good idea - because you can not dose it that much.
Most ppl. still dose 0,1- 0,2ppm urea as small addition and together with other nitrate sources.
In one high light tank I dose ~0,5ppm urea as addition, but I don´t keep any sensitive animals there and never meassured anything.
There may be some nitrite/ammonia spices for short time, but i dont know how much or high at last.
So certainly for any sensitive animals this may be harmfull (depending on PH and other things) and doing so not recommended.
Depending on yours tap, you may better go with a mix:
Ca(NO3)2 and Mg(NO3)2x6H20